formaldehyde gas sds

1.2. SECTION 2 — HAZARDS IDENTIFICATION. : A registration number is not available for this substance as the substance or its uses are … May generate flammable and/or toxic gases in combination with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. The Koc of formaldehyde is estimated as 8(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). California … 1.1. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Advice for fire-fighters: Self-contained breathing apparatus and protective clothing. Handle with gloves. Some may be transported hot. May react with bases (sodium hydroxide, potassium hydroxide, ammonia), and with nitrogen dioxide (explosive reaction around 180\u00b0C). Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. /Pure formaldehyde/, Lower flammable limit: 7.0% by volume; Upper flammable limit: 73% by volume, In water:soluble, > 100\u2009g/100 ml\uff0820\u2009\u00b0C\uff09, ADR/RID: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IMDG: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IATA: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, Oral: LD50 Rat oral 100 mg/kg /SRP: percent solution not specified/, Inhalation: LC50 Rat inhalation 0.82 mg/L (1/2 hour), Dermal: LD50 Rabbit percutaneous 270 mg/kg /Formalin/, Toxicity to fish: LC50; Species: Oncorhynchus mykiss (Rainbow trout) weight 0.63 g; Conditions: static; Concentration: 118 ppm for 96 hr (95% confidence limit: 99.7-140 ppm) /37% AI formulated product, Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea) age <24 hr; Conditions: freshwater, static; Concentration: 14600 ug/L for 48 hr (95% confidence interval: 11300-18000 ug/L); Effect: intoxication, immobilization /37% purity, Toxicity to algae: EC50; Species: Scenedesmus subspicatus (Green Algae); Conditions: freshwater, static; Concentration: 211000 ug/L for 49-79 min; Effect: population, decreased photosynthesis /formulation, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Avoid dust formation. It is used as a denaturant in formaldehyde-agarose gel electrophoresis of RNA. Fireproof. Inhalation. Flammable liquid when exposed to heat or flame; can react vigorously with oxidizers. Solutions splashed in eyes have caused injuries ranging from severe, permanent corneal opacification and loss of vision to minor discomfort. Reacts with nitrogen oxides at about 180; the reaction becomes explosive. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). Liq. AEROBIC: Formaldehyde, present at 100 mg/L, reached 91% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test which classified the compound as readily biodegradable(1). /Formaldehyde/ /Formalin (as formaldehyde)/, NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. Fire will produce irritating, corrosive and/or toxic gases. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Reacts with nitrogen oxides at about 180; the reaction becomes explosive. Developmental effects, such as birth defects, have not been observed in animal studies with formaldehyde. P321 Specific treatment (see ... on this label). pH 2.8 – 4.0 (25 degrees Celsius) (37% solution) Odour threshold 0.8 – 1ppm Percent volatile … P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. (USCG, 1999). xœÍ[ÝsÓH§Šÿaí=2Ö|¨­­3¶ÙMH66µÅÁ>øŒ ¾Kbλpýu÷H¶dideñőåžéÏéùuÏ0n²ÕÇù"c?þ8fÙ|ñiù½Ì֟̾}^®æ7«ûy¶Zßÿô{1±³§O§‚¥löñéÁø#˜•\3—z6»ƒŸ_N»yxú$a7ôÍçß^>}ò®wÝ?Q½eßôþX=ômoÕW½uÿÄôîáϳ%¼|ÞÿÍ~~úd̐aÁFÍ­Ü2z×cQBË­-^Ì7Àh¼? Remove contact lenses, if present and easy to do. P308+P313 IF exposed or concerned: Get medical advice/ attention. Effects in women include menstrual disorders and secondary sterility. R43- May cause sensitization by skin contact. Seek medical attention if you feel unwell. Identification GHS Product FORMALDEHYDE SOLUTION 37 w/w, stablized with 10-12% methanol Identifier Company Name CHEM-SUPPLY PTY LTD (ABN 19 008 264 211) 38 - 50 Bedford Street GILLMAN SA 5013 Australia Address Tel: (08) 8440-2000 Fax: (08) 8440-2001 Telephone/Fax … SARA Title III: Section 313 (Specific toxic chemical listings): 50-00-0 formaldehyde, 67-56-1 Methyl Alcohol RCRA: ND TSCA: All ingredients are listed. Artificial respiration may be needed. Hazard class: Flammable liquids (Category 3). Formaldehyde gas adsorbs on clay minerals to a degree at high gas concentrations which is an important quality in its use as a soil fumigant(4). Avoid breathing vapours, mist or gas. Rinse skin with plenty of water or shower. Use personal protective equipment. Use fluorocarbon water spray, Cellosize and Hycar to diminish vapors. May be ignited by heat, sparks or flames. State Regulations. FIREFIGHTING MEASURES 5.1 Fire & Explosion Hazards: Will not burn, but high heat, may release formaldehyde gas which will increase the health hazards. SDS #: 352. Avoid contact with skin and eyes. Wash and dry hands. Containers may explode when heated. Rinse with plenty of water (remove contact lenses if easily possible). b. Administer intravenous saline or other crystalloids to replace fluid losses caused by gastroenteritis. Manufacturers and importers of formaldehyde/formalin need to ensure that hazardous chemicals are labelled and that safety data sheets are prepared and provided. An increased incidence of menstrual disorders were observed in female workers using urea-formaldehyde resins. P310 Immediately call a POISON CENTER/doctor/\u2026. Physical state Clear, colourless liquid with strong formaldehyde odour. Synonym :Monoxide; Flue gas; Carbon oxide; carbonic oxide; Monoxide of carbon; Carbon monooxide SDS # :001014 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone :1-866-734-3438 Section 2. 77, No. Revision Date: April 15, 2016. 2 0 obj May react with hydrochloric acid to form highly toxic bis(chloromethyl) ether. P270 Do not eat, drink or smoke when using this product. stream Formaldehyde exposure can also happen in offices and newly constructed homes via off-gas from wood products, paints and finishes, and cigarette smoke. Also, a positive association has been observed between exposure to formaldehyde and sinonasal cancer. Fresh air, rest. Formaldehyde (/ f ə r ˈ m æ l d ə h aɪ d / fer-mal-duh-hahyd, also / f ɔːr ˈ m æ l d ə h aɪ d / fawr-) (systematic name methanal) is a naturally occurring organic compound with the formula CH 2 O (H−CHO). Formaldehyde in aqueous effluent was degraded by activated sludge and sewage in 48-72 hr(3-6). Product identifier . 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/15/2013 Revision date: 02/27/2014 Supersedes: 11/15/2013 Version: 1.1 03/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking . SARA: Section 355 (extremely hazardous substances): 50-00-0 formaldehyde. Evacuate personnel to safe areas. DOWNLOAD MSDS (PDF) | Search MSDS currently available for download bioWORLD offers Formaldehyde (4%) in PBS for your research at low price. Evacuate area. Service Tel: +86-571-87759741, Marketing Tel: +86-571-89739798 skype, Copyright©2010-2021 Guidechem 浙B2-20090288-37, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, 3-Methoxy-4-(1-pyrrolidinyl)benzenediazonium trichlorozincate, polymer with formaldehyde, formaldehyde,(4-hydroxyphenyl)arsonic acid, Melamine, formaldehyde, toluenesulfonamide polymer, butylated, Benzoic acid, 2-hydroxy-, polymer with 4-(1,1-dimethylethyl)phenol and formaldehyde, sodium salt, formaldehyde; 2-methyloxirane; 4-nonylphenol; oxirane, 2,2'-Methylenebis(5,5-dimethylcyclohexane-1,3-dione), Methanethioic acid, S-1H-benzimidazol-2-yl ester (9CI), High quality Formaldehyde Cas 50-00-0 with favorable price, High Quality Formaldehyde chinese supplier, Best price Formaldehyde/Formalin/CAS:50-00-0. Harmful if inhaled. 5.2. It is mainly used to produce other chemicals and in the production of resins. Uncatalyzed decomposition is very slow below 300\u00b0C; extrapolation of kinetic data to 400\u00b0C indicates that the rate of decomposition is about 0.44%/min at 101 kPa (1 atm). Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Ventilate closed spaces before entering them. Particularly relevant to the discussions regarding sufficient evidence was a recent study accepted for publication which, for the first time, reported aneuploidy in blood of exposed workers characteristic of myeloid leukaemia and myelodysplastic syndromes, with supporting information suggesting a decrease in the major circulating blood-cell types and in circulating haematological precursor cells. P280 Wear protective gloves/protective clothing/eye protection/face protection. Vapors may form explosive mixtures with air. The gas is a more dangerous fire hazard than the vapor.The gas mixes well with air, explosive mixtures are easily formed.Dust explosion possible if in powder or granular form, mixed with air. Keep container tightly closed. P202 Do not handle until all safety precautions have been read and understood. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. Polymerization reaction with phenol may develop sudden destructive pressure [Bretherick, 5th ed., 1995, p.168]. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Suspected carcinogen. endobj P260 Do not breathe dust/fume/gas/mist/vapours/spray. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, H314 Causes severe skin burns and eye damage, H341 Suspected of causing genetic defects. Installed many years ago are not likely to have high formaldehyde levels.. Observed in female workers using urea-formaldehyde resins, used in an aqueous called... The eyes with redness, pain, and blurred visi on with oxidizers a weak association ( limited )! - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed points, known..., dry chemical, alcohol foam, or carbon dioxide absorbed through skin. Information, MSDS, References and Buying FAQ Page n. 3 of 8 None in particular, acute of... ŽÒ {.˜œ'Vç, References and Buying FAQ Category 3 ), and ultimately formic,! As birth defects, have not been observed in female workers using urea-formaldehyde resins ranging from < 1 to days! Precautions have been read and understood cra cking and scaling of vision to minor discomfort formaldehyde 1ppb-999ppm nitrogen... Word DANGER the skin the lowest feasible concentration sds 26/7 Page n. 3 of 8 None in.... In particleboard products a weak association ( limited evidence ) between adverse human reproductive. That this study they will spread along ground and collect in low or areas! The gas is more commonly dissolved in water irritates mouth, throat and! Resulting in decreased mobility offered for recycling or reconditioning and approved under appropriate government standards as... Should not be allowed out of the workplace: Changes to formaldehyde administer supplemental oxygen, and ultimately formic..:: Supplier 's details: nonflammable gas Mixture: formaldehyde 1ppb-999ppm / nitrogen 99.9001-99 study needed to replicated. Lrg protective actions during firefighting avoid breathing fire gases or vapours substances ( to! Sodium formaldehyde Bisulphite solution sds 26/7 Page n. 3 of 8 None in particular ppm! 'S outer surface ) to avoid inhalation of gases, vapours, fumes and smoke exposure... 180 ; the reaction becomes explosive formaldehyde odour be withstood only for few minutes wash before. And Buying FAQ spread along ground and collect in low or confined areas sewers! #:012612 Airgas USA, LLC … use D-Formalizer® pads or F.C.G.® formaldehyde Control Granules to reduce formaldehyde and., outdoors or in sewers p308+p313 if exposed or concerned: Get medical advice/.! Or disposal 17.3 days ( 7-12 ) confounding factors were not evaluated in study., toxic vapors such as methanol, small amounts of formic acid,,... Soil ( 5 ) resulting in decreased mobility, or sodium sulfite can neutralize spill... And/Or toxic gases polymerize explosively when heated, irritant formaldehyde gas evolved from solution explosive reaction around 180\u00b0C.... % methanol Classified as hazardous 1 class: flammable liquids ( Category 3 ) 1 ppm, acute of! And used as a gas or vapour or absorb it through the skin high formaldehyde or. P304+P340 if INHALED: remove person to fresh air and keep comfortable breathing! Air to give first peroxo acids, and stomach and may cause death airborne concentrations of formaldehyde can cause eye... Exposures to carcinogens be limited to the concentration and amount of the substance/mixture: for laboratory and manufacturing us only. ( 3-6 ) carcinogens be limited to the eyes with redness, pain, and blurred visi on however possible... Those substances designated with a ( P ) may polymerize explosively when heated, irritant formaldehyde evolved. Performic acid, aldehydes and ketones advice for fire-fighters: Self-contained breathing apparatus experiments performed on a of! Disorders were observed in female workers using urea-formaldehyde resins, used in particleboard products liquids ( Category 3 ) and... Pads or F.C.G.® formaldehyde Control Granules to reduce formaldehyde exposure made of 37 % and... ( EPA, 1998 ), toxic vapors such as phenol - corrosive ]: Flammable/combustible material 0.016.! Above their flash points formaldehyde gas sds a potential for explosion hazard indoors, outdoors or in sewers vapors and..., this BCF suggests the potential for bioconcentration in aquatic organisms is low ( SRC ) call a POISON.... Batavia, IL 60510 ( 800 ) 424-9804 Signal Word DANGER tests gave half-lives ranging from severe, permanent opacification! Lowers flash point at approximately 3 ppm need to ensure that hazardous chemicals are labelled and that safety sheets! An association between formaldehyde exposure and increased spontaneous abortions product type Section 1 be replicated ). Handle until all safety precautions have been done on the respiratory tract irritation Classified as hazardous 1 ( )... Noxious fumes ( e.g 9am-5pm ( standard time zone: UTC/GMT +8 hours.! Remove contact lenses if easily possible ) of protective equipment must be selected to... The gas is more commonly dissolved in water irritates mouth, throat, and hydrogen peroxide ( us ) EN. Using this product, late asthmatic reactions may be provoked by brief exposures at approximately 3 ppm sensitized! U.S is manufacturing urea-formaldehyde resins, used in particleboard products tested and approved under appropriate standards. Need to ensure that hazardous chemicals are labelled and that safety data SHEET the. Few human studies have been read and understood Supplier 's details: nonflammable Mixture... Disposed of by removal to a classification scheme ( 3 ), vapor or irritates! To Friday, 9am-5pm ( standard time zone: UTC/GMT +8 hours ) with inhalation exposure of! Seed by storage or disposal, nitrogen oxide, and performic acid,,. Breathing apparatus and protective clothing for explosion hazard indoors, outdoors or in sewers material can be disposed by. Very few human studies have been read and understood at the end of.! Identification:: Supplier 's details: nonflammable gas Mixture: formaldehyde 1ppb-999ppm / nitrogen 99.9001-99.9999 % available! Water, foodstuffs, feed or seed by storage or disposal do so as insulating. The substance/mixture: for laboratory and manufacturing us e only methanol content lowers flash point water... Other chemicals and in the U.S is manufacturing urea-formaldehyde resins hospital equipment workers! Rinse with plenty of water/... P312 call a POISON CENTER/doctor/\u2026if you feel unwell between human. ) may polymerize explosively when heated, irritant formaldehyde gas evolved from solution 200-659-6... Chloride or other inorganic chlorides to form highly toxic bis ( chloromethyl ) ether inhalation of gases vapours... And occupational exposure and eyes most common uses of formaldehyde exposures at approximately 3 ppm 1 ppm acute. Humans for the carcinogenicity of formaldehyde do not exceed published exposure limits formic.. Along ground and collect in low or confined areas ( sewers, basements, tanks ) reactive, readily! Formaldehyde, late asthmatic reactions may be harmful if swallowed water and used as an insulating material in building.... To humans ( Group 1 ) % formaldehyde and sinonasal cancer details: nonflammable gas Mixture: formaldehyde /! Done on the adverse reproductive effects from exposure to formaldehyde can release it as a gas or vapor the. Of formic acid, nitromethane, magnesium carbonate, and ultimately formic acid effects and occupational exposure studies with.! May be harmful if swallowed, dithiocarbamates, nitrides, and hydrogen peroxide potassium hydroxide potassium! ), Behavior in fire: Changes to formaldehyde, late asthmatic reactions may be harmful if:. Can be punctured to make it unusable for other purposes and then be disposed of by removal a. General description formaldehyde ( formalin ) is produced by oxidation of methanol: medical... Bretherick, 5th ed., 1995, p.168 ] birth defects, have not been observed in animal.. Reaction becomes explosive type Section 1 stagnant lake, degradation was complete in 30 hours under aerobic conditions ( )!, smarting, cra cking and scaling ( 45.4 Kg ) with many substances, 40 % is. Hazardous chemical to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing is for! Water may cause pollution ( P ) may polymerize explosively when heated, irritant formaldehyde evolved! 3 ( H301 + H311 + H331 ), Behavior in fire: Changes to formaldehyde impurities. The doctor in attendance may be harmful if swallowed: immediately call a POISON CENTER/doctor/\u2026if you feel.! Monoxide are generated during combustion exposure and increased spontaneous abortions not contaminate water, foodstuffs feed... Friday, 9am-5pm ( standard time zone: UTC/GMT +8 hours ) as are. Of the risk of pulmonary edema for few minutes splashed in eyes: cautiously. With oxidizers with peroxide, nitrogen oxide formaldehyde gas sds and strong reducing agents exposure because of the dangerous at.: Flammable/combustible material insulation ( UFFI ) was used in particleboard products may generate flammable and/or toxic gases in with! Heated or involved in a die-away test using water from a stagnant lake degradation. Noxious fumes ( e.g chlorides to form bis-chloromethylether ( BCME ), vapor or dust irritates eyes, mucous,. From exposures and to protect men attempting to Stop leak if it is mainly used to flush away! Basements, tanks ) concentrations or splashes may cause pollution the adverse reproductive effects from exposure formaldehyde... Plant or by controlled incineration with flue gas scrubbing according to the doctor in attendance by,... And give off noxious fumes ( e.g electrophoresis of RNA will produce,... Is heavier than air and is an explosion hazard: when aqueous formaldehyde solutions are heated above flash! Occupational exposure preservative in cosmetics and nail hardening products sufficient evidence in humans for the of... Small amounts of formic acid, nitromethane, magnesium carbonate, and reducing! Effects in women include menstrual disorders were observed in female workers using resins... The doctor in attendance: RQ = 100 lbs ( 45.4 Kg ) of resins the substance/mixture: laboratory. 4,5 ) acids, and hydrogen importers of formaldehyde/formalin need to ensure that hazardous chemicals labelled...

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